Effect of nickel oxide concentration on titanium oxide bilayer photoanode for dye-sensitized solar cell application
Document Type
Article
Publication Title
Journal of Materials Science: Materials in Electronics
Abstract
The mesoporous titanium oxide has attracted significant attention as a photoanode material for Dye-Sensitized Solar Cells (DSSCs). In the present work, we coated a planar NiO layer on the TiO2 film to minimize charge recombination with the dye and/or electrolyte molecules. The structural, morphological, elemental, optical, and electrical properties of the TiO2 and bi-layered TiO2/NiO films were studied using various characterization techniques. DSSCs based on N3 dye-sensitized TiO2 and bi-layered TiO2/NiO films were fabricated using PI as the redox electrolyte. The photocurrent density–voltage (J–V) characteristics of the DSSCs were studied using a solar simulator. Various parameters, such as open-circuit voltage (Voc), short-circuit photocurrent density (Jsc), and fill factor (FF), were calculated from the J–V characteristics. DSSCs based on bi-layered TiO2/NiO films showed superior performance compared to bare TiO2 films. The J–V characteristics of bilayer film shows enhanced open-circuit voltage (Voc) ~ 0.56 V, short-circuit current density (Jsc) ~ 2.14 mA/cm2, fill factor (FF) ~ 75%, and efficiency (ƞ) ~ 0.91%. The TiO2/NiO solar cell showed a ~ 28% increase in efficiency compared to TiO2-based DSSC. Hence, the bi-layered TiO2/NiO films have potential applications in optoelectronic and photovoltaic devices.
DOI
10.1007/s10854-024-13141-y
Publication Date
7-1-2024
Recommended Citation
Mujawar, Almas; Shaikh, Kashmira; Lokhande, Prasad; and Supekar, Abhijit, "Effect of nickel oxide concentration on titanium oxide bilayer photoanode for dye-sensitized solar cell application" (2024). Open Access archive. 10290.
https://impressions.manipal.edu/open-access-archive/10290
