Influence of Different Heat Treatment Temperatures on the Microstructure and Corrosion Behaviour of Dual-Phase EN8 Steel in 0.5 M Sulphuric Acid Solution

Document Type

Article

Publication Title

Journal of Bio- and Tribo-Corrosion

Abstract

Dual-phase steels provide an excellent combination of strength and ductility, as well as improved energy absorption and anti-corrosion protection properties. This research aims at evaluating the microstructure and corrosion behaviour of EN8 steel under different heat treatment temperatures in 0.5 M sulphuric acid solution (H2SO4) using the EIS, potentiodynamic polarization, and gravimetric method (weight-loss method). Austenitizing is performed at 973 K, 1023 K, 1063 K, and 1173 K for 2 h followed by quenching in water to form a ferrite–martensite (F–M) dual-phase structure. From the results, it is seen that the corrosion rate increased with different heat treatment conditions depending on the change in the phase when immersed in 0.5 M H2SO4 at the temperature of 303 K, 313 K, 323 K, and 333 K. This work investigates the energy of activation, enthalpy, and entropy of activation. For dual-phase steel containing ferrite and martensite, the corrosion behaviour depends on the amount of martensite and ferrite. As the austenitization temperature increases from 1023 to 1173 K, the amount of martensite increases. This is reflected in the increase of micro galvanic corrosion cells in the region between the ferrite and martensite phases, which acts as active corrosion centres. The normalized specimen showed greater corrosion resistance compared to the water-quenched specimen at 1173 K. This is due to the presence of lower carbon content for normalized dual-phase steel containing ferrite–pearlite phase than the ferrite–martensite phase present in specimen austenitized at 1173 K. Surface characterization and XRD confirmed the corrosion behaviour of the specimens under investigation.

DOI

10.1007/s40735-022-00689-7

Publication Date

12-1-2022

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